Preparation and characterization Al3+-bentonite Turen Malang for esterification fatty acid (palmitic acid, oleic acid and linoleic acid)

Abdulloh Abdulloh; Nanik Siti Aminah; Triyono; Mudasir; Wega Trisunaryanti

doi:10.1063/1.4943331

Preparation and characterization Al³⁺-bentonite Turen Malang for esterification fatty acid (palmitic acid, oleic acid and linoleic acid)

Abdulloh Abdulloh, Nanik Siti Aminah, Triyono, Mudasir, Wega Trisunaryanti

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

2 Citations (Scopus)

Abstract

Catalyst preparation and characterization of Al³⁺-bentonite for esterification of palmitic acid, oleic acid and linoleic acid has been done. Al³⁺-bentonite catalyst was prepared from natural bentonite of Turen Malang through cation exchange reaction using AlCl₃ solution. The catalysts obtained were characterized by XRD, XRF, pyridine-FTIR and surface area analyser using the BET method. Catalyst activity test of Al³⁺-bentonite for esterification reaction was done at 65°C using molar ratio of metanol-fatty acid of 30:1 and 0.25?g of Al³⁺-bentonite catalyst for the period of , 1, 2, 3, 4 and 5 hours. Based on the characterization results, the Al³⁺-bentonite Turen Malang catalyst has a d-spacing of 15.63 ?, acid sites of Brönsted and Lewis respectively of 230.79?μmol/g and 99.39?μmol/g, surface area of 507.3?m²/g and the average of radius pore of 20.09 Å. GC-MS analysis results of the oil phase after esterification reaction showed the formation of biodiesel (FAME: Fatty acid methyl ester), namely methyl palmitate, methyl oleate and methyl linoleate. The number of conversions resulted in esterification reaction using Al³⁺-bentonite Turen Malang catalyst was 74.61%, 37.75%, and 20, 93% for the esterification of palmitic acid, oleic acid and linoleic acid respectively.

Original language	English
Title of host publication	5th International Conference and Workshop on Basic and Applied Sciences, ICOWOBAS 2015
Editors	Moh. Yasin, Sulaiman W. Harun
Publisher	American Institute of Physics Inc.
ISBN (Electronic)	9780735413641
DOIs	https://doi.org/10.1063/1.4943331
Publication status	Published - 15 Mar 2016
Event	5th International Conference and Workshop on Basic and Applied Sciences, ICOWOBAS 2015 - Surabaya, Indonesia Duration: 16 Oct 2015 → 17 Oct 2015

Publication series

Name	AIP Conference Proceedings
Volume	1718
ISSN (Print)	0094-243X
ISSN (Electronic)	1551-7616

Conference

Conference	5th International Conference and Workshop on Basic and Applied Sciences, ICOWOBAS 2015
Country/Territory	Indonesia
City	Surabaya
Period	16/10/15 → 17/10/15

Keywords

bentonite
esterification
linoleic acid
oleic acid
palmitic acid

Access to Document

10.1063/1.4943331

Cite this

Abdulloh, A., Aminah, N. S., Triyono, Mudasir, & Trisunaryanti, W. (2016). Preparation and characterization Al³⁺-bentonite Turen Malang for esterification fatty acid (palmitic acid, oleic acid and linoleic acid). In M. Yasin, & S. W. Harun (Eds.), 5th International Conference and Workshop on Basic and Applied Sciences, ICOWOBAS 2015 Article 070001 (AIP Conference Proceedings; Vol. 1718). American Institute of Physics Inc.. https://doi.org/10.1063/1.4943331

Abdulloh, Abdulloh ; Aminah, Nanik Siti ; Triyono et al. / Preparation and characterization Al³⁺-bentonite Turen Malang for esterification fatty acid (palmitic acid, oleic acid and linoleic acid). 5th International Conference and Workshop on Basic and Applied Sciences, ICOWOBAS 2015. editor / Moh. Yasin ; Sulaiman W. Harun. American Institute of Physics Inc., 2016. (AIP Conference Proceedings).

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title = "Preparation and characterization Al3+-bentonite Turen Malang for esterification fatty acid (palmitic acid, oleic acid and linoleic acid)",

abstract = "Catalyst preparation and characterization of Al3+-bentonite for esterification of palmitic acid, oleic acid and linoleic acid has been done. Al3+-bentonite catalyst was prepared from natural bentonite of Turen Malang through cation exchange reaction using AlCl3 solution. The catalysts obtained were characterized by XRD, XRF, pyridine-FTIR and surface area analyser using the BET method. Catalyst activity test of Al3+-bentonite for esterification reaction was done at 65°C using molar ratio of metanol-fatty acid of 30:1 and 0.25?g of Al3+-bentonite catalyst for the period of , 1, 2, 3, 4 and 5 hours. Based on the characterization results, the Al3+-bentonite Turen Malang catalyst has a d-spacing of 15.63 ?, acid sites of Br{\"o}nsted and Lewis respectively of 230.79?μmol/g and 99.39?μmol/g, surface area of 507.3?m2/g and the average of radius pore of 20.09 {\AA}. GC-MS analysis results of the oil phase after esterification reaction showed the formation of biodiesel (FAME: Fatty acid methyl ester), namely methyl palmitate, methyl oleate and methyl linoleate. The number of conversions resulted in esterification reaction using Al3+-bentonite Turen Malang catalyst was 74.61%, 37.75%, and 20, 93% for the esterification of palmitic acid, oleic acid and linoleic acid respectively.",

keywords = "bentonite, esterification, linoleic acid, oleic acid, palmitic acid",

author = "Abdulloh Abdulloh and Aminah, {Nanik Siti} and Triyono and Mudasir and Wega Trisunaryanti",

note = "Publisher Copyright: {\textcopyright} 2016 AIP Publishing LLC.; 5th International Conference and Workshop on Basic and Applied Sciences, ICOWOBAS 2015 ; Conference date: 16-10-2015 Through 17-10-2015",

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day = "15",

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Abdulloh, A , Aminah, NS, Triyono, Mudasir & Trisunaryanti, W 2016, Preparation and characterization Al³⁺-bentonite Turen Malang for esterification fatty acid (palmitic acid, oleic acid and linoleic acid). in M Yasin & SW Harun (eds), 5th International Conference and Workshop on Basic and Applied Sciences, ICOWOBAS 2015., 070001, AIP Conference Proceedings, vol. 1718, American Institute of Physics Inc., 5th International Conference and Workshop on Basic and Applied Sciences, ICOWOBAS 2015, Surabaya, Indonesia, 16/10/15. https://doi.org/10.1063/1.4943331

Preparation and characterization Al³⁺-bentonite Turen Malang for esterification fatty acid (palmitic acid, oleic acid and linoleic acid). / Abdulloh, Abdulloh ; Aminah, Nanik Siti; Triyono et al.
5th International Conference and Workshop on Basic and Applied Sciences, ICOWOBAS 2015. ed. / Moh. Yasin; Sulaiman W. Harun. American Institute of Physics Inc., 2016. 070001 (AIP Conference Proceedings; Vol. 1718).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

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T1 - Preparation and characterization Al3+-bentonite Turen Malang for esterification fatty acid (palmitic acid, oleic acid and linoleic acid)

AU - Abdulloh, Abdulloh

AU - Aminah, Nanik Siti

AU - Triyono,

AU - Mudasir,

AU - Trisunaryanti, Wega

PY - 2016/3/15

Y1 - 2016/3/15

N2 - Catalyst preparation and characterization of Al3+-bentonite for esterification of palmitic acid, oleic acid and linoleic acid has been done. Al3+-bentonite catalyst was prepared from natural bentonite of Turen Malang through cation exchange reaction using AlCl3 solution. The catalysts obtained were characterized by XRD, XRF, pyridine-FTIR and surface area analyser using the BET method. Catalyst activity test of Al3+-bentonite for esterification reaction was done at 65°C using molar ratio of metanol-fatty acid of 30:1 and 0.25?g of Al3+-bentonite catalyst for the period of , 1, 2, 3, 4 and 5 hours. Based on the characterization results, the Al3+-bentonite Turen Malang catalyst has a d-spacing of 15.63 ?, acid sites of Brönsted and Lewis respectively of 230.79?μmol/g and 99.39?μmol/g, surface area of 507.3?m2/g and the average of radius pore of 20.09 Å. GC-MS analysis results of the oil phase after esterification reaction showed the formation of biodiesel (FAME: Fatty acid methyl ester), namely methyl palmitate, methyl oleate and methyl linoleate. The number of conversions resulted in esterification reaction using Al3+-bentonite Turen Malang catalyst was 74.61%, 37.75%, and 20, 93% for the esterification of palmitic acid, oleic acid and linoleic acid respectively.

AB - Catalyst preparation and characterization of Al3+-bentonite for esterification of palmitic acid, oleic acid and linoleic acid has been done. Al3+-bentonite catalyst was prepared from natural bentonite of Turen Malang through cation exchange reaction using AlCl3 solution. The catalysts obtained were characterized by XRD, XRF, pyridine-FTIR and surface area analyser using the BET method. Catalyst activity test of Al3+-bentonite for esterification reaction was done at 65°C using molar ratio of metanol-fatty acid of 30:1 and 0.25?g of Al3+-bentonite catalyst for the period of , 1, 2, 3, 4 and 5 hours. Based on the characterization results, the Al3+-bentonite Turen Malang catalyst has a d-spacing of 15.63 ?, acid sites of Brönsted and Lewis respectively of 230.79?μmol/g and 99.39?μmol/g, surface area of 507.3?m2/g and the average of radius pore of 20.09 Å. GC-MS analysis results of the oil phase after esterification reaction showed the formation of biodiesel (FAME: Fatty acid methyl ester), namely methyl palmitate, methyl oleate and methyl linoleate. The number of conversions resulted in esterification reaction using Al3+-bentonite Turen Malang catalyst was 74.61%, 37.75%, and 20, 93% for the esterification of palmitic acid, oleic acid and linoleic acid respectively.

KW - bentonite

KW - esterification

KW - linoleic acid

KW - oleic acid

KW - palmitic acid

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Abdulloh A , Aminah NS, Triyono, Mudasir, Trisunaryanti W. Preparation and characterization Al³⁺-bentonite Turen Malang for esterification fatty acid (palmitic acid, oleic acid and linoleic acid). In Yasin M, Harun SW, editors, 5th International Conference and Workshop on Basic and Applied Sciences, ICOWOBAS 2015. American Institute of Physics Inc. 2016. 070001. (AIP Conference Proceedings). doi: 10.1063/1.4943331