TY - JOUR
T1 - Effect of spinach (Spinacia oleracea) leaf extract on the aluminum (Al) as a green corrosion inhibitor in HCl medium
AU - Kusuma, Heri Septya
AU - Danera, Geza Satya
AU - Maulana, Agung Dwiza
AU - Rahmasari, Mayang
AU - Nida, Risma Atiqotun
AU - Amenaghawon, Andrew Nosakhare
AU - Darmokoesoemo, Handoko
AU - Zarrouk, Abdelkader
N1 - Publisher Copyright:
© 2024 The Author(s)
PY - 2024/12
Y1 - 2024/12
N2 - Green corrosion inhibitors have recently attracted much attention due to their non-toxic properties, especially plant extracts. This study used spinach leaf extract (Spinacia oleracea) as a corrosion inhibitor on aluminum in an HCl medium. Spinach leaf extract (Spinacia oleracea) was obtained by maceration method, using ethanol as the solvent, which was then distilled to purify the extract. The corrosion inhibition properties were studied by the gravimetric method. The results showed that spinach leaf extract (Spinacia oleracea) can efficiently decrease the corrosion rate of aluminum in an HCl medium, achieving a maximum efficiency of 96.7742 %. Spinach leaf extract (Spinacia oleracea) formed a protective layer on the aluminum surface via adsorption and chemisorption, thus increasing surface coverage and blocking mass transfers. As the inhibitor concentration increases, the corrosion rate decreases, and the corrosion inhibition efficiency increases. This study shows that spinach leaf extract (Spinacia oleracea) is a viable organic corrosion inhibitor option with high efficiency.
AB - Green corrosion inhibitors have recently attracted much attention due to their non-toxic properties, especially plant extracts. This study used spinach leaf extract (Spinacia oleracea) as a corrosion inhibitor on aluminum in an HCl medium. Spinach leaf extract (Spinacia oleracea) was obtained by maceration method, using ethanol as the solvent, which was then distilled to purify the extract. The corrosion inhibition properties were studied by the gravimetric method. The results showed that spinach leaf extract (Spinacia oleracea) can efficiently decrease the corrosion rate of aluminum in an HCl medium, achieving a maximum efficiency of 96.7742 %. Spinach leaf extract (Spinacia oleracea) formed a protective layer on the aluminum surface via adsorption and chemisorption, thus increasing surface coverage and blocking mass transfers. As the inhibitor concentration increases, the corrosion rate decreases, and the corrosion inhibition efficiency increases. This study shows that spinach leaf extract (Spinacia oleracea) is a viable organic corrosion inhibitor option with high efficiency.
KW - Aluminum
KW - Box-behnken design
KW - Green corrosion inhibitor
KW - HCl
KW - Spinach leaf extract
UR - http://www.scopus.com/inward/record.url?scp=85204625213&partnerID=8YFLogxK
U2 - 10.1016/j.hybadv.2024.100283
DO - 10.1016/j.hybadv.2024.100283
M3 - Article
AN - SCOPUS:85204625213
SN - 2773-207X
VL - 7
JO - Hybrid Advances
JF - Hybrid Advances
M1 - 100283
ER -