Effect of metal ion Fe(III) on the performance of chlorophyll as photosensitizers on dye sensitized solar cell

Harsasi Setyawati; Handoko Darmokoesoemo; Anggy Tamara Ayu Ningtyas; Yassine Kadmi; Hicham Elmsellem; Heri Septya Kusuma

doi:10.1016/j.rinp.2017.08.009

Effect of metal ion Fe(III) on the performance of chlorophyll as photosensitizers on dye sensitized solar cell

Harsasi Setyawati, Handoko Darmokoesoemo, Anggy Tamara Ayu Ningtyas, Yassine Kadmi, Hicham Elmsellem, Heri Septya Kusuma

Research output: Contribution to journal › Article › peer-review

37 Citations (Scopus)

Abstract

The energy crisis is a major problem facing the world today and will need a renewable energy source that is environmentally friendly; one of these is the dye sensitized solar cell (DSSC). DSSC is photochemical electric cell that can convert solar energy into electrical energy. This research aims to study the characteristics of chlorophyll compounds with the addition of metal ions Fe(III) and to determine the effect of Fe(III) on the performance of chlorophyll as a photosensitizer in the DSSC. The formation of complex compounds of Fe(III)-chlorophyll is shown by the phenomenon of metal ligand charge transfer (MLCT) at a wavelength of 263.00 nm and absorption transition d-d at 745.00 nm. Fourier transform infrared characterization of the binding of Fe-O complex compounds appears at 486.06 cm⁻¹. The complex compound of Fe(III)-chlorophyll has a magnetic moment value of 9.62 Bohr Magneton (BM). The existence of ion Fe(III) in chlorophyll can improve the performance of chlorophyll as a dye sensitizer with a maximum current of 4.00 mA/cm², maximum voltage of 0.18 volts and efficiency values of 1.35%.

Original language	English
Pages (from-to)	2907-2918
Number of pages	12
Journal	Results in Physics
Volume	7
DOIs	https://doi.org/10.1016/j.rinp.2017.08.009
Publication status	Published - 2017

Keywords

Dye sensitized solar cell
Fe(III)-chlorophyll
Metal ligand charge transfer
Photosensitizer

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.rinp.2017.08.009

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title = "Effect of metal ion Fe(III) on the performance of chlorophyll as photosensitizers on dye sensitized solar cell",

abstract = "The energy crisis is a major problem facing the world today and will need a renewable energy source that is environmentally friendly; one of these is the dye sensitized solar cell (DSSC). DSSC is photochemical electric cell that can convert solar energy into electrical energy. This research aims to study the characteristics of chlorophyll compounds with the addition of metal ions Fe(III) and to determine the effect of Fe(III) on the performance of chlorophyll as a photosensitizer in the DSSC. The formation of complex compounds of Fe(III)-chlorophyll is shown by the phenomenon of metal ligand charge transfer (MLCT) at a wavelength of 263.00 nm and absorption transition d-d at 745.00 nm. Fourier transform infrared characterization of the binding of Fe-O complex compounds appears at 486.06 cm−1. The complex compound of Fe(III)-chlorophyll has a magnetic moment value of 9.62 Bohr Magneton (BM). The existence of ion Fe(III) in chlorophyll can improve the performance of chlorophyll as a dye sensitizer with a maximum current of 4.00 mA/cm2, maximum voltage of 0.18 volts and efficiency values of 1.35%.",

keywords = "Dye sensitized solar cell, Fe(III)-chlorophyll, Metal ligand charge transfer, Photosensitizer",

author = "Harsasi Setyawati and Handoko Darmokoesoemo and Ningtyas, {Anggy Tamara Ayu} and Yassine Kadmi and Hicham Elmsellem and Kusuma, {Heri Septya}",

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AU - Setyawati, Harsasi

AU - Darmokoesoemo, Handoko

AU - Ningtyas, Anggy Tamara Ayu

AU - Kadmi, Yassine

AU - Elmsellem, Hicham

AU - Kusuma, Heri Septya

PY - 2017

Y1 - 2017

N2 - The energy crisis is a major problem facing the world today and will need a renewable energy source that is environmentally friendly; one of these is the dye sensitized solar cell (DSSC). DSSC is photochemical electric cell that can convert solar energy into electrical energy. This research aims to study the characteristics of chlorophyll compounds with the addition of metal ions Fe(III) and to determine the effect of Fe(III) on the performance of chlorophyll as a photosensitizer in the DSSC. The formation of complex compounds of Fe(III)-chlorophyll is shown by the phenomenon of metal ligand charge transfer (MLCT) at a wavelength of 263.00 nm and absorption transition d-d at 745.00 nm. Fourier transform infrared characterization of the binding of Fe-O complex compounds appears at 486.06 cm−1. The complex compound of Fe(III)-chlorophyll has a magnetic moment value of 9.62 Bohr Magneton (BM). The existence of ion Fe(III) in chlorophyll can improve the performance of chlorophyll as a dye sensitizer with a maximum current of 4.00 mA/cm2, maximum voltage of 0.18 volts and efficiency values of 1.35%.

AB - The energy crisis is a major problem facing the world today and will need a renewable energy source that is environmentally friendly; one of these is the dye sensitized solar cell (DSSC). DSSC is photochemical electric cell that can convert solar energy into electrical energy. This research aims to study the characteristics of chlorophyll compounds with the addition of metal ions Fe(III) and to determine the effect of Fe(III) on the performance of chlorophyll as a photosensitizer in the DSSC. The formation of complex compounds of Fe(III)-chlorophyll is shown by the phenomenon of metal ligand charge transfer (MLCT) at a wavelength of 263.00 nm and absorption transition d-d at 745.00 nm. Fourier transform infrared characterization of the binding of Fe-O complex compounds appears at 486.06 cm−1. The complex compound of Fe(III)-chlorophyll has a magnetic moment value of 9.62 Bohr Magneton (BM). The existence of ion Fe(III) in chlorophyll can improve the performance of chlorophyll as a dye sensitizer with a maximum current of 4.00 mA/cm2, maximum voltage of 0.18 volts and efficiency values of 1.35%.

KW - Dye sensitized solar cell

KW - Fe(III)-chlorophyll

KW - Metal ligand charge transfer

KW - Photosensitizer

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M3 - Article

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SN - 2211-3797

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EP - 2918

JO - Results in Physics

JF - Results in Physics

ER -

Effect of metal ion Fe(III) on the performance of chlorophyll as photosensitizers on dye sensitized solar cell

Abstract

Keywords

UN SDGs

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